Nanomaterials @ Interfaces Research Group

Prof. Yuval Golan's Research Group

Hierarchical assembly of ultranarrow alkylamine-coated ZnS nanorods

A Synchrotron surface X-ray diffraction study

Nataly Belman, Somobrata Acharya, Oleg Konovalov, Alexei Vorobiev, Jacob Israelachvili, Shlomo Efrima,Yuval Golan

The packing of anisotropic ultranarrow nanoparticles (r ≤ 0.5 nm) in Langmuir films was investigated for two types of nanoparticles: short ZnS wires coated with tetradecylamine and ZnS rods coated with octadecylamine. In situ grazing Incidence small-angle X-ray scattering (GISAXS) revealed the formation, even under zero pressure, of ordered superstructures on the water surface consisting of alternating nanoparticles. A hierarchical "packing model" is proposed, based on GISAXS, transmission electron microscopy, thermogravimetric analysis, and grazing incidence X-ray diffraction of pure surfactant Langmuir films.

Publication language English
Pages 3858-3864
Journal Nano Letters
Volume 8
Issue number 11
Publication status Published - 01.11.2008

ASJC Scopus subject areas

Bioengineering
General Chemistry
General Materials Science
Condensed Matter Physics
Mechanical Engineering
Access to Document
10.1021/nl802287h
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Link to publication in Scopus