Yonatan Sivan

Senior Academic

Assistance of metal nanoparticles in photocatalysis-nothing more than a classical heat source

In a recent paper, we derived a self-consistent theory of the steady-state electron distribution of a metal under continuous wave illumination which treats thermal and non-thermal effects on the same footing. Here, we re-derive the main analytical results of that study from very simple arguments, and draw a series of conclusions which contradict claims made in previous studies of the steady-state distribution. In particular, we show that the faster chemical reactions reported in many previous papers are extremely unlikely to originate from high energy non-thermal electrons. Instead, the faster reactions very likely originate from a purely thermal effect.

Publication language English
Pages 215-233
Journal Faraday Discussions
Volume 214
Publication status Published - 01.01.2019

ASJC Scopus subject areas

Physical and Theoretical Chemistry
Access to Document
10.1039/c8fd00147b
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Link to publication in Scopus