
Yonatan Sivan
Senior Academic
Assistance of metal nanoparticles in photocatalysis-nothing more than a classical heat source
In a recent paper, we derived a self-consistent theory of the steady-state electron distribution of a metal under continuous wave illumination which treats thermal and non-thermal effects on the same footing. Here, we re-derive the main analytical results of that study from very simple arguments, and draw a series of conclusions which contradict claims made in previous studies of the steady-state distribution. In particular, we show that the faster chemical reactions reported in many previous papers are extremely unlikely to originate from high energy non-thermal electrons. Instead, the faster reactions very likely originate from a purely thermal effect.
| Publication language | English |
| Pages | 215-233 |
| Journal | Faraday Discussions |
| Volume | 214 |
| Publication status | Published - 01.01.2019 |
ASJC Scopus subject areas
Physical and Theoretical Chemistry