Msrg (1)

Menny Shalom

Senior Academic

Controlled carbon nitride growth on surfaces for hydrogen evolution electrodes

Menny Shalom, Sixto Gimenez, Florian Schipper, Isaac Herraiz-Cardona, Juan Bisquert, Markus Antonietti

Efficient and low-cost electrocatalysts for the hydrogen evolution reaction are highly desired for future renewable energy systems. Described herein is the reduction of water to hydrogen using a metal-free carbon nitride electrocatalyst which operates in neutral and alkaline environments. An efficient, easy, and general method for growing ordered carbon nitride on different electrodes was developed. The metal-free catalyst demonstrates low overpotential values, which are comparable to those of non-noble metals, with reasonable current densities. The facile deposition method enables the fabrication of many electronic and photoelectronic devices based on carbon nitride for renewable energy applications. A scoff at non-nobles: The reduction of water to hydrogen using a metal-free carbon nitride (C3N 4) electrocatalyst in neutral and alkaline environments is demonstrated. An efficient, easy, and general method for growing ordered carbon nitride on different electrodes was developed. The metal-free catalyst demonstrates low overpotential values, which are comparable to non-noble metals, with reasonable current densities.

Publication language English
Pages 3654-3658
Journal Angewandte Chemie - International Edition
Volume 53
Issue number 14
Publication status Published - 01.04.2014

Keywords

carbon nitride
electrochemistry
hydrogen
supramolecular chemistry
surface chemistry

ASJC Scopus subject areas

Catalysis
General Chemistry

Sustainable Development Goals

SDG 7 - Affordable and Clean Energy
Access to Document
10.1002/anie.201309415
Other files and links
Link to publication in Scopus