Msrg (1)

Menny Shalom

Senior Academic

Energy-Efficient Hydrogen Generation via Peroxide-Mediated Electrocatalytic Pathways

Alagar Raja Kottaichamy, Thamaraichelvan Marichelvam, Jonathan Tzadikov, Roni Cohen Vaza, Michael Volokh, Shmuel Barzilai, Menny Shalom

Hydrogen (H2) production through water electrolysis is a promising route for sustainable energy storage. However, conventional water electrolysis faces several challenges, such as large thermodynamic potential gaps and sluggish oxygen evolution kinetics, which lead to high electricity consumption and limitations in H2 storage and transportation. A promising approach to overcoming these hurdles is hybrid water electrolysis, which integrates alternative, thermodynamically favorable reactions at the anode to enhance efficiency. In this study, we explore how peroxide redox electrocatalysis can address critical barriers in sustainable H2 production, storage, and transport. By leveraging a cost-effective and highly efficient peroxide redox electrocatalyst, we demonstrate various electrolysis configurations that significantly reduce the required cell voltage—from the standard 1.23 V down to −0.06 V, highlighting its potential for scalable and economically viable electrolysis methodologies for H2 production.

Publication language English
Volume 64
Issue number 28
Publication status Published - 07.07.2025

Keywords

Alkaline peroxide electrolyzer
Bipolar-Ions gradient energy
Hydrogen evolution
Peroxide redox electrocatalysis

ASJC Scopus subject areas

Catalysis
General Chemistry

Sustainable Development Goals

SDG 7 - Affordable and Clean Energy
Access to Document
10.1002/anie.202502735
Other files and links
Link to publication in Scopus