Msrg (1)

Menny Shalom

Senior Academic

Robust Carbon Nitride-Based Thermoset Coatings for Surface Modification and Photochemistry

Baris Kumru, Jesús Barrio, Jianrui Zhang, Markus Antonietti, Menny Shalom, Bernhard V.K.J. Schmidt

Herein, the convenient visible light-induced photografting of hydroxyl ethyl methacrylate onto graphitic carbon nitride (g-CN) is described, leading to well-dispersible g-CN-based precursor polymers that can be injected. Mixing with citric acid as the cross-linker and heating leads to stable thermoset coatings. The process is versatile and easy to perform, leading to g-CN-based coatings. Moreover, the coating can be further functionalized/modified via grafting of other polymer chains, and the resulting structure is useful as photocatalytic surface or as photoelectrode.

Publication language English
Pages 9462-9469
Volume 11
Issue number 9
Publication status Published - 06.03.2019

Keywords

carbon nitride
coating
dispersion
photoactive surface
photoelectrochemistry
photopolymerization
thermoset

ASJC Scopus subject areas

General Materials Science
Access to Document
10.1021/acsami.8b21670
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Link to publication in Scopus